Mark, Digger and Tim judge as legal and outlaw distillers compete to make the best rum. Constructing stills of their own design and mashing in their own raw ingredients, only one will survive elimination to earn the title of Master Distiller.

Mark, Digger and Tim judge as top amateur distillers from both sides of the law compete to make mezcal, the moonshine of Mexico. Using agave mash, regional recipes and even meat, only one competitor will earn the title of Master Distiller.