Mark, Digger and Tim judge as top amateur distillers from both sides of the law compete to make mezcal, the moonshine of Mexico. Using agave mash, regional recipes and even meat, only one competitor will earn the title of Master Distiller.

Tickle hosts as Appalachia's most notorious moonshiners go head-to-head in a moonshine distilling competition. Mark, Digger and Tim run their own secret recipes to be judged by the public to determine once and for all who makes the best shine.