Moonshine has an Irish forefather, a high-proof spirit called Poitin, still outlawed in Northern Ireland. For this challenge, three skilled distillers bring their own ingredients and rebel spirit, but only one will be crowned Master Distiller.

Four outlaw distillers, Amanda, Richard, Kelly and Tater, battle for their place in shiner history. Facing real-world outlaw challenges and two eliminations, only one will emerge as Master of the Backwoods.