Moonshiners stars Richard Landry, Killer Beaz and Howard Thompson compete to turn spicy peppers into tasty, high-proof moonshine. But it takes a master moonshiner to run a balanced hot liquor, and every misstep comes at the price of sweat and tears.

Mark, Digger and Tim judge as three top distillers go head-to-head to distill off-the-shelf beers into high-proof liquor. Only the distiller who can produce the best-tasting beer-shine will be crowned Master Distiller.