From their villa HQ in the Italian hills, the two Matt's head to Bologna where they get a masterclass in making that city's most famous dish… with mixed reviews from a scary Italian mama. Joe Fattorini fulfils a lifelong dream to bid on a barrel of wine at Burgundy's famous Vente des Vins auction. Does he succeed, and just where will he keep all 288 bottles!? Spanish super chef Elena Arzak lets us into her London restaurant for a taste of her favourite wine and creates a perfect dish to accompany it. And wine expert Amelia Singer explores the German roots of one of Australia's greatest wine regions, the Barossa Valley.

Matthew Goode and Matthew Rhys star in this series about the stories behind some of the world's most fascinating wines. From their villa HQ in the Italian hills they travel north to the mountainous region of Trentino where they meet an inspirational winemaker who ages her wine in clay urns. Joe Fattorini heads to Hong Kong to explore China's ‘red obsession' and a WW2 bunker where the most exclusive wine tastings in the world take place. Yorkshire Chef Frances Atkins shares her love of white wine and creates a very unusual dish to match it. Amelia Singer visits Seppeltsfield in Australia's Barossa Valley where she comes face to face with some snapshots of her own family's history.