Dominic West joins James Purefoy to taste wines at the beautiful HQ in the Douro Valley. Matthew Goode and James learn about the Portuguese Age of Discoveries in Lisbon, and Matthew Rhys takes Joe for lunch at a Jewish restaurant in New York. Joe Fattorini and Amelia Singer lead a wine tour in Madeira.

Matthew Goode and James Purefoy visit the cork harvest in the Alentejo, where James has a cry. Dominic West joins James to taste wines at the beautiful HQ in the Douro Valley. In Thailand Joe Fattorini gets his head and mouth around Thai foods and flavours researching his wine list for a pop-up Thai restaurant back in London. In New York Matthew Rhys and Joe pair dim sum and Chinese wine.