Matthew Goode and James Purefoy visit the cork harvest in the Alentejo, where James has a cry. Dominic West joins James to taste wines at the beautiful HQ in the Douro Valley. In Thailand Joe Fattorini gets his head and mouth around Thai foods and flavours researching his wine list for a pop-up Thai restaurant back in London. In New York Matthew Rhys and Joe pair dim sum and Chinese wine. 

Matthew and James are north Portugal - the region of Vinho Verde where they explore Portugal's historic relationship with the catholic church and Matthew repents his sins. Joe Fattorini and Matthew Rhys go all Goodfellas at Matthew's favourite Italian restaurant in Brooklyn. And Joe finds out how Queen Victoria was the original influencer in Germany.