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When a leading scientific researcher is killed by poisoning, Patrick Jane takes a personal interest in the case when he learns the prime suspect is the victim's wife, and Jane's former psychiatrist.
When the CBI uncovers three arson cases, Patrick Jane suspects the only surviving member of a National Guard unit of murdering his friends, and goes undercover to prove it.
Patrick Jane, enticed by the promise from a convicted murderer that he'll reveal information about Red John upon his release, becomes singularly focused and quits the CBI in order to prove the prisoner is innocent.