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On the way to the next contest, Ash and friends meet a trainer who is training for a competition known as the Pokéathlon. Interested in what it is, they decide to go check it out. Ash then decide to enter the competition.
While on the way to the next contest town, Gible falls in a river. Buizel saves it. This attracts the attention of a trainer, who wants to have a battle between Buizel and his Mr. Mime. Ash agrees. Mr. Mime proves to be too strong for Buizel though. Following this loss, Buizel is determined to get stronger and defeat Mr. Mime.
Contest day has finally arrived and Dawn is trying to perfect Mamoswine and Cyndaquil's "Flame-Ice" combination. However, a Plusle and Minun shows up. Dawn begins to act strangely, revealing that she has a bad experience with a Plusle and Minun in the past. Things are made worse when Dawn's mean spirited rival Ursula shows up. Ursula is ready to defeat Dawn. Can Dawn keep it together for the contest?