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Graham Norton is joined by Rosamund Pike, comedian Michael McIntyre, Andrew Lloyd Webber and Coldplay, who also perform their single Everglow.
Graham is joined by Oscar-winning actor and director Ben Affleck, starring in new action thriller The Accountant, Sir David Attenborough, who is presenting BBC One's Planet Earth II, and ex-Doctor Who star Matt Smith and Wolf Hall's Claire Foy, starring as Prince Philip and the Queen in Netflix series The Crown.
Sting performs I Can't Stop Thinking About You from his new album.
Graham is joined by Tom Hanks, starring in Sully as the pilot who crash-landed his airliner in the Hudson river with no loss of life, British star Gemma Arterton, playing Joan of Arc in the classic play Saint Joan, Joseph Gordon-Levitt, playing the NSA whistleblower in Snowden, and athlete Mo Farah. With music from Olly Murs, who performs Grow Up.