The Explorers, led by Amegio, have appeared to seize Terrapagos. A fierce battle is about to begin in the ancient castle! Freed and Amegio have fought countless battles together. What will be the outcome of this match? And can Rico and Roy, who have grown stronger through their many adventures, defeat Jill and Conia? Furthermore, the Explorers Hambell, Sango, and Onyx also join the fray—!?

Based on a sighting of a black Rayquaza obtained by Dot, the Rising Volteckers arrive in the Wild Area of the Galar region. However, the information turns out to be false... Seeing Dot's frustration, Rico suggests they make curry together, and they decide to take a break in the Wild Area. Meanwhile, at the Explorers headquarters, the executives are all gathered together...