The kitchen gets steamy when Derek Simcik, named Sexiest Chef, goes up against Philadelphia's haute chef, Sylva Senat. Chopped's Chris Santos and Marc Murphy choose which chef will burn Bobby Flay.

Things get shrewd when Iron Chef's Alex Guarnaschelli and Alton Brown join forces. It's up to partners in business and in life, chefs Lisa Carlson and Carrie Summer, to outsmart the one and only Bobby Flay!