Best Baker's Marcela Valladolid pairs up with the Cake Boss himself, Buddy Valastro, to try and score a sweet victory against Bobby Flay. Chefs Jocelyn Gragg and Kathleen McDaniel, two southern belles from Atlanta with a propensity for pastry, aren't here to sugarcoat it -- they're looking for a win.

Food Network's Michael Symon enlists his pal, TV host Clinton Kelly, to distract Bobby Flay with their friendship. They get additional help from a French master, Chef Sylvain Delpique, and an Italian bread master, Chef Jackie Mazza, who bring the tension to a boil in the kitchen.