The team visits the home of the Spencer family, Althorp in Northamptonshire. It dates back five centuries and has an impressive art collection with more than 650 paintings. Antiques experts Charles Hanson and Will Axon uncover movie memorabilia, including a photo signed by Charlie Chaplin, and a box of decorative studs by fashion house Cartier. Paul Martin examines Althorp's collection of portrait paintings by renowned artist Joshua Reynolds.

Paul Martin presents from the town of Reading in Berkshire. Antique experts Anita Manning and David Harper find objects to take off to auction. Anita comes across a biscuit barrel shaped like a Scottish curling stone, which reminds her of home, and David gets excited by a silver box with a jasper stone top. Paul takes a trip to a Herbarium where he learns about the important work that plant collectors have done through the centuries.