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Ash and friends are continuing their journey when a group of kids suddenly appear in front of them. They begin throwing mud balls at Ash and his friends and as they run off, a Trubbish steals Ash's hat. They then give chase.
On the way to Nacrene City, Ash and friends encounter the Pokémon Dwebble. However, this Dwebble does not have a rock on its back as it should. It begins to make a new shell, but then three more Dwebble show up and trouble starts.
Ash and friends meet a girl named Bianca. Professor Juniper has asked Bianca to meet up with them in order to deliver a badge case to Ash. As Bianca gets the case out it is all dusty from sitting at the bottom of her bag. Suddenly a Minccino comes by and snatches the case and runs off with it. Ash and friends give chase.