Jools welcomes a brand new collaboration consisting of Academy Award-nominated actress and singer Jessie Buckley and Brit Award-winning producer and ex-Suede guitarist Bernard Butler, who perform a couple of tracks from their forthcoming album, a collection of 12 mesmerising new songs entitled For All Our Days that Tear the Heart. They chat to Jools about their collaboration and their choices from the Later… archives of performances by Leonard Cohen and Paul Buchanan.

There are three debuts on this week's show, starting with south Londoner Poppy Ajudha, who has collaborated with the likes of Tom Misch and Nubya Garcia and performs her single PLAYGOD from her debut album The Power in Us. The album has been described by critics as a 'genre fluid blend of jazz, R&B, soul, rock and pop' that offers 'powerful therapy in troubled times'. Poppy also performs, with Jools at the piano, a classic song she grew up listening to.

Also making their debut are Brisbane electro-pop quartet Confidence Man, fronted by two powerhouse performers known as Janet Planet and Sugar Bones, who consider the likes of Bono, Noel Gallagher and Elton John amongst their fans. They perform their catchy, infectious tune Holiday, a song that perfectly encapsulates the sound of their latest album Tilt and 'taps into the hedonistic feeling of all the best EDM.'

And completing the line-up are London based rock'n'roll band Warmduscher, who are renowned for their raucous, high-energy performances. Their lineup includes previous members of Fat White Family, and they have just released their fourth LP, At the Hotspot, produced by Hot Chip's Joe Goddard and Al Doyle.

Returning to the show after an eight-year break, we welcome back Scottish singer-songwriter Paolo Nutini, who performs songs from his upcoming fourth studio album Last Night In The Bittersweet, a record that saw him write over a hundred songs during its making.
 
Making her debut on the show is Bristolian breakthrough artist Katy J Pearson, who is inspired by the likes of Kate Bush and Fleetwood Mac and performs Talk Over Town from her upcoming second LP, which is co-produced by PJ Harvey collaborator Ali Chant and producer of the moment Dan Carey.
 
Jools chats to legendary producer William Orbit about some of the records he has worked on in his career spanning six decades, including albums by Blur, Madonna and U2. He selects a performance from the archive by Amadou & Mariam. William also performs a song with singer-songwriter Polly Scattergood.
 
Returning to the show are twin sisters from Paris, Ibeyi, who have just released their third album Spell 31, which sees them collaborate with Jorja Smith, Pa Salieu and Berwyn. They perform their track Sister 2 Sister, which they say is the first song they've written about their relationship as twins.
 
And also returning are Oxford indie rockers Foals with a couple of tracks from their upcoming new album Life Is Yours, including the single 2am, which was written during lockdown about their longing for nightlife and parties. Frontman Yannis also chats to Jools about the record and his desire to write a traditional Greek music album.

And as part of an evening celebrating Pride month on BBC Two, we delve into the archive to relive the Scissor Sisters debut on the show.